February 10, 2021

New mix could double concrete’s carbon uptake

WEST LAFAYETTE, Ind. — Concrete is not glamorous. It is the workhorse of building materials: versatile, durable, and almost universally ubiquitous, with 30 billion tons of concrete produced every year. Cement, a component of concrete, produces 8% of the world’s carbon footprint.

Looking to lower that percentage, Purdue University engineers have discovered a way to make concrete more sustainable. Their new recipe for concrete has the potential to cut carbon emissions dramatically, creating building blocks for a better world.

A team lead by Mirian Velay-Lizancos, an assistant professor of civil engineering at Purdue, proposes adding small amounts of nanoscale titanium dioxide to the cement paste that makes up concrete. The team found that titanium dioxide, a powdery substance known best for its uses in sunscreen, paints, plastics and food preservatives, enhances concrete’s natural ability to sequester carbon dioxide.

velay-concrete Marian Velay Lizancos and her students are developing concrete that can sequester carbon dioxide more successfully and efficiently than traditional mixes. (Purdue University photo/John Underwood)

The team discovered that adding only small amounts of nano-titanium dioxide nearly doubles concrete’s absorption of the problematic greenhouse gas. The study recently appeared in the scientific journal Construction and Building Materials. A YouTube video of the work is available.

Velay-Lizancos studies concrete and works to make it a more sustainable building material. Concrete, a variable mixture of water, cement paste, and aggregates such as sand and gravel, was invented millennia ago. Since then, it has changed to suit civilizations’ evolving needs and available materials. The concrete in the Pyramids needed to stand up to heat and wind. The concrete in Roman aqueducts needed to carry millions of gallons of water. Modern concrete needs to be strong, durable, economical, and as sustainable as possible. Manufacturing concrete is an energy and resource-intensive process. Traditional concrete naturally absorbs carbon dioxide — just not very much and not very quickly.

“We can’t wait decades for concrete to absorb the carbon dioxide produced in its manufacturing process,” Velay-Lizancos said. “My team is making the concrete itself absorb carbon dioxide faster and in greater volumes. We’re not trying to change the way we use concrete; we’re making the concrete work for us.”

The staggering amount of concrete used across the world today—in bridges, in roads and infrastructure, in buildings and monuments, dams and pipe systems—means that any slight improvement in the carbon footprint of concrete could add up to massive effects worldwide.

The changes Velay-Lizancos’ team proposes would result in more than a slight change. Her research indicates that including titanium dioxide in the cement mix used to make concrete can double to the amount of carbon dioxide it naturally sequesters in the same amount of time. This effect is in addition to concrete’s well-studied photocatalytic effect, where ultraviolet light from sunshine interacts with concrete to help concrete oxidize harmful nitrogen oxide gases into nitrates.

“We are living in a building environment,” Velay-Lizancos said. “There is no doubt that improving the sustainability of concrete, the most used construction material in the world, would mean a giant leap for sustainable development.”

Initially, Velay-Lizancos and two of her doctoral students, Carlos Moro and Vito Francioso,  were studying how titanium dioxide might interact with cement to make concrete stronger and how curing temperature might affect those interactions. They noticed that some of their concrete samples that included nano-titanium dioxide absorbed carbon dioxide from the surrounding air faster than other samples.

Further investigation revealed that adding nano-titanium dioxide to the concrete mix decreased the size of calcium hydroxide molecules, making it vastly more efficient at absorbing carbon dioxide than other cement pastes. The addition accelerated the rate of carbon absorption and increased the total volume of carbon dioxide it can absorb.

“I have always wanted to help others, to do something meaningful, something impactful,” Velay-Lizancos said. “This work is a way I can help others. Our research may lead to lower net carbon dioxide emissions. Knowing what you are doing may help stop climate change makes you wake up every day with energy to work harder than the day before.”

Her future research will focus on more ways to make concrete more sustainable, more durable and an even better building material for the future. 

About Purdue University

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Writer, Media contact: Brittany Steff; 765-494-7833; bsteff@purdue.edu

Source: Mirian Velay-Lizancos  mvelayli@purdue.edu

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ABSTRACT

Modification of CO2 capture and pore structure of hardened cement paste made with nano-TiO2 addition: Influence of water-to-cement ratio and CO2 exposure age

Carlos Moro, Vito Francioso, Mirian Velay-Lizancos

DOI: 10.1016/j.conbuildmat.2020.122131

This paper studies the effects of nano-TiO2 in CO2 sequestration of hardened cement paste depending on the water-to-cement ratio (w/c) and the pore structure. Twelve cement paste mixtures were prepared with four different percentages of nano-TiO2 (0%, 0.5%, 1%, 2%) and three w/c (0.45, 0.50, 0.55). Samples were exposed for 24 h to a CO2 environment at two different ages (14 and 28 days). Thermogravimetric analysis and 3D X-Ray scans of the pore structure were performed on exposed and unexposed samples. Results showed that nano-TiO2 produces an improvement in the CO2 uptake until a certain percentage. This maximum percentage depends on exposure age and w/c. Nano-TiO2 produces a reduction in porosity and an increment of calcium hydroxide (CH) reactivity, which have opposite effects on CO2 uptake. These two competing mechanisms may explain why nano-TiO2 can be beneficial or detrimental for the CO2 uptake as a function of w/c ratio and age.


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