January 26, 2023

Researchers tailor thickness of conducting nitrides and oxides to enhance their photonic applications

Key research finding

Purdue University researchers found that by tailoring the film thickness of conducting nitrides and oxides, specifically plasmonic titanium nitride (TiN) and aluminum-doped zinc oxide (AZO), they can control the materials’ optical properties, most notably their epsilon near zero (ENZ) behaviors. The TiN and AZO materials developed at Purdue also feature the lowest reported optical losses. This provides novel applications for the telecommunications field and furthers the study of many optical nonlinearities. 

Vladimir M. Shalaev and Alexandra Boltasseva, Purdue professors of electrical and computer engineering, and their team of researchers, led by then-postdoctoral researcher Soham Saha, investigated this method of controlling the ENZ point, the wavelength at which a material is neither dielectric nor metallic. When light travels through an ENZ material, its group velocity slows to near zero, and it’s able to interact with the material for a longer period. This gives rise to many interesting nonlinearities. However, with most conventional materials, the ENZ point is fixed and difficult to move.

What the researchers demonstrated is that the thickness association of the optical properties is one of the easiest things to manipulate, enabling them to grow films with different ENZ properties using the same growth environment. By tailoring the thickness of material films and controlling light absorption near the ENZ regime, researchers can study absolute ENZ physics at many different wavelength ranges. The enables a wide range of nonlinear optical phenomena, including all-optical switching, time refraction and high-harmonic generation.

Purdue professors’ expertise

Shalaev, the Bob and Anne Burnett Distinguished Professor of Electrical and Computer Engineering, has been a pioneer in the fields of transformation optics, metamaterials, nanophotonics and plasmonics since 1990. He is the scientific director of nanophotonics at Purdue’s Birck Nanotechnology Center.

Boltasseva is the Ron and Dotty Garvin Tonjes Professor of Electrical and Computer Engineering at Purdue. She pioneered the field of alternative plasmonic materials and the application of conducting oxides, nitrides and MXenes in photonics.

Journal Article Publication

The study is published in the journal Advanced Materials. An abstract is available online.


Purdue researchers were supported by the following funding sources:

U.S. Department of Energy, Basic Energy Sciences, Division of Materials Sciences and Engineering. Grant number DE-SC0017717

Office of Naval Research. Grant number N00014-20-1-2199

Air Force Office of Scientific Research. Grant number FA9550-20-1-0124

U.S. Department of Energy, Basic Energy Sciences. Grant number DE-AC02-06CH11357

Brief summary of methods

Researchers developed a low-loss, polycrystalline films of TiN on silicon by reactive magnetron sputtering. AZO was grown by pulsed laser deposition on the as-grown TiN. They investigated the cause of the thickness-dependent optical properties through spectroscopic ellipsometry, atomic force microscopy and transmission electron microscopy, connecting the optical properties to their structural properties. As a proof of concept of a dynamic, tunable device, researchers demonstrated all-optical switching of the resonators using an interband pump, showing picosecond relaxation times.

About Purdue University

Purdue University is a top public research institution developing practical solutions to today’s toughest challenges. Ranked in each of the last five years as one of the 10 Most Innovative universities in the United States by U.S. News & World Report, Purdue delivers world-changing research and out-of-this-world discovery. Committed to hands-on and online, real-world learning, Purdue offers a transformative education to all. Committed to affordability and accessibility, Purdue has frozen tuition and most fees at 2012-13 levels, enabling more students than ever to graduate debt-free. See how Purdue never stops in the persistent pursuit of the next giant leap at https://stories.purdue.edu.

Media contact: Kayla Wiles, 765-494-2432, wiles5@purdue.edu

Source: Vladimir M. Shalaev

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