December 21, 2009

Method makes refineries more efficient

The researchers have demonstrated their method on petroleum plants that separate crude, showing that 70 of the new sequences they identified could enable oil refineries to improve the energy efficiency of this step anywhere from 6 percent to 48 percent, said Rakesh Agrawal, the Winthrop E. Stone Distinguished Professor of Chemical Engineering.

"This is important because improving efficiency by 10 percent at a refinery processing 250,000 barrels per day would save in excess of $12 million a year if oil were priced at $70 a barrel," said Agrawal, who is working with doctoral student Vishesh Shah. "And that's just a single refinery. For the U.S. petroleum industry as a whole, this is a huge potential savings."

Research findings appeared online this month in the AIChE Journal, the official peer-reviewed journal of the American Institute of Chemical Engineers, and will be included in a future issue of the magazine.

Chemical plants spend from 50 percent to 70 percent of their energy in "separations," which are usually distillation steps required to separate a raw material into various products. In the case of petroleum, four distillation columns are needed to separate raw crude into five separate components - naphtha, kerosene, diesel fuel, gas oil and heavy residue. Some of these components are later used to make gasoline.

"Separations are a huge part of what chemical plants do," Agrawal said. "Improving efficiency by only a few percentage points translates into major savings. For every 100 barrels of oil distilled, nearly two barrels go into supplying energy for distillation. That's a lot of oil."

Crude petroleum is fed into the system, heated and vaporized. Vapor rises up the first column, and the product is collected in a condenser at the top. The process is repeated in additional columns, with the number of columns depending on how many components are to be separated.

But the distillation is more energy efficient depending on the order in which the columns are operated.

"There are many ways to arrange the columns," Agrawal said.

Shah created a computer algorithm that identifies all of the possible sequences and then determines which require the least heat and energy. The Purdue researchers used their new technique to determine there are nearly 6,000 possible sequences for the four columns used in petroleum distillation.

"Once we know all of the possible ways they can be arranged, then we can tell you which ones have the potential to be the most energy efficient," Agrawal said.

Petroleum refineries have been using the same sequence for about 75 years, and it is the most energy efficient of the sequences known to industry, the Purdue researchers confirmed using their new method.

The researchers also determined, however, that 70 of the new sequences identified have potential to consume less energy than the sequence now used by industry. Those 70 sequences range from being 6 percent to 48 percent more energy efficient than the method currently in use.

"However, just because a particular sequence would be more energy efficient doesn't mean it would be practical for industry to implement," Agrawal said. "There are a lot of challenges. Some are easy to build and just involve trivial retrofitting, and some are more difficult. So we'll need to work with companies and refinery experts to determine which sequences could be built."

The U.S. Department of Energy's Industrial Technology Program funded the research.

The journal paper was written by Shah and Agrawal. Previous, related work also involved Arun Giridhar, a Purdue postdoctoral researcher. As a supplement to the paper, the researchers also provided more than a gigabyte of data on all of the distillation sequences identified using the technique for the separation of mixtures containing up to eight components.

Purdue has filed a patent application for the new crude distillation sequences.

Writer: Emil Venere, 765-494-4709, venere@purdue.edu

Source:    Rakesh Agrawal, 765-494-2257, agrawalr@purdue.edu

Purdue News Service: (765) 494-2096; purduenews@purdue.edu

Note to Journalists: The paper is available at the AIChE Journal, https://www3.interscience.wiley.com/cgi-bin/fulltext/123189974/HTMLSTART  

We describe a simple-to-use "matrix" method for obtaining all the basic distillation configurations and additional thermally coupled configurations that separate a zeotropic multicomponent feed into essentially pure product streams. This provides an opportunity to ranklist the configurations for a given application subject to criteria of interest. The only information needed to generate the configurations is the number of components in the feed. We have successfully enumerated all the configurations for feeds containing up to eight components. The method can also be used to generate non-distillation as well as hybrid separation configurations, and even easy-to-retrofit configurations. We illustrate the use of this method by applying it to the highly energy-intensive problem of petroleum crude distillation. We have identified more than 70 new configurations that could potentially have lower heat duty than the existing configuration. A significant number of these could reduce the heat demand by nearly 50%.

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